Laser Induced Fluoresence and Fluoresence Depletion Spectroscopy of the Jet-Cooled CF3S Radical
نویسندگان
چکیده
David E. Powers, Michael Pushkarsky and Terry A. Miller Laser Spectroscopy Facility The Ohio State University 120 W. 18th Avenue Columbus OH 43210 The spectrum of the CF3S free radical has been observed for the first time cooled in a supersonic free jet expansion. Both ”bright” and ”dark” levels of the à state have been observed using a combination of laser induced fluoresence and fluoresence depletion spectroscopy. The photofragmentation of CF3S is shown to be very mode specific.
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Rotational Analyses of the Laser Induced Fluorescence Excitation Spectra of Jet-Cooled CF3O and CF3S
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